- Costs. In 2002, typical cells had a catalyst content of US$1000 per kilowatt of electric power output. In 2008 UTC Power has 400kw Fuel cells for $1,000,000 per 400kW installed costs. The goal is to reduce the cost in order to compete with current market technologies including gasoline internal combustion engines. Many companies are working on techniques to reduce cost in a variety of ways including reducing the amount of platinum needed in each individual cell. Ballard Power Systems have experiments with a catalyst enhanced with carbon silk which allows a 30% reduction (1 mg/cm² to 0.7 mg/cm²) in platinum usage without reduction in performance.[4]
- The production costs of the PEM (proton exchange membrane). The Nafion® membrane currently costs €400/m². This, and the Toyota PEM and 3M PEM membrane can be replaced with the ITM Power membrane (a hydrocarbon polymer), resulting in a price of ~€4/m². in 2005 Ballard Power Systems announced that its fuel cells will use Solupor®, a porous polyethylene film patented by DSM.[5][6]
- Water and air management[7] (in PEMFCs). In this type of fuel cell, the membrane must be hydrated, requiring water to be evaporated at precisely the same rate that it is produced. If water is evaporated too quickly, the membrane dries, resistance across it increases, and eventually it will crack, creating a gas "short circuit" where hydrogen and oxygen combine directly, generating heat that will damage the fuel cell. If the water is evaporated too slowly, the electrodes will flood, preventing the reactants from reaching the catalyst and stopping the reaction. Methods to manage water in cells are being developed like electroosmotic pumps focusing on flow control. Just as in a combustion engine, a steady ratio between the reactant and oxygen is necessary to keep the fuel cell operating efficiently.
- Temperature management. The same temperature must be maintained throughout the cell in order to prevent destruction of the cell through thermal loading. This is particularly challenging as the 2H2 + O2 -> 2H20 reaction is highly exothermic, so a large quantity of heat is generated within the fuel cell.
- Durability, service life, and special requirements for some type of cells. Stationary applications typically require more than 40,000 hours of reliable operation at a temperature of -35 °C to 40 °C, while automotive fuel cells require a 5,000 hour lifespan (the equivalent of 150,000 miles) under extreme temperatures. Automotive engines must also be able to start reliably at -30 °C and have a high power to volume ratio (typically 2.5 kW per liter).
- Limited carbon monoxide tolerance of the anode.
Wednesday, March 26, 2008
Fuel cell design issues
Meeting fuel cell vehicle Challenges Together
Automakers, fuel cell developers, component suppliers, government agencies, and others are working hard to accelerate the introduction of FCVs. Partnerships such as the DOE-led FreedomCAR initiative and the California Fuel Cell Partnership have been formed to encourage private companies and government agencies to work together to move these vehicles toward commercialization.
FreedomCAR
- Cheaper to operate
- Pollution-free
- Competitively priced
- Free from imported oil
California Fuel Cell Partnership (CaFCP)
The California Fuel Cell Partnership is a collaboration of auto companies, fuel providers, fuel cell technology companies, and government agencies demonstrating fuel cell electric vehicles in California under day-to-day driving conditions. The goals of the partnership are to test and demonstrate the viability of FCVs and related technology under real-world conditions, move them toward commercialization, and increase public awareness. The Partnership expects to place about 60 FCVs and fuel cell buses on the road by 2003.http://www.fueleconomy.gov/feg/fuelcell.shtml
Fuel cell design
n essence, a fuel cell works by catalysis, separating the component electrons and protons of the reactant fuel, and forcing the electrons to travel through a circuit, hence converting them to electrical power. The catalyst is typically comprised of a platinum group metal or alloy. Another catalytic process takes the electrons back in, combining them with the protons and the oxidant to form waste products (typically simple compounds like water and carbon dioxide). 
Condensation of water produced by a PEMFC on the air channel wall. The gold wire around the cell ensures the collection of electric current.[2]
In the archetypal hydrogen–oxygen proton exchange membrane fuel cell (PEMFC) design, a proton-conducting polymer membrane, (the electrolyte), separates the anode and cathode sides. This was called a "solid polymer electrolyte fuel cell" (SPEFC) in the early 1970s, before the proton exchange mechanism was well-understood. (Notice that "polymer electrolyte membrane" and "proton exchange membrane" result in the same acronym.)
On the anode side, hydrogen diffuses to the anode catalyst where it later dissociates into protons and electrons. These protons often react with oxidants causing them to become what is commonly reffered to as multi-facilitated proton membranes (MFPM). The protons are conducted through the membrane to the cathode, but the electrons are forced to travel in an external circuit (supplying power) because the membrane is electrically insulating. On the cathode catalyst, oxygen molecules react with the electrons (which have traveled through the external circuit) and protons to form water — in this example, the only waste product, either liquid or vapor.
In addition to this pure hydrogen type, there are hydrocarbon fuels for fuel cells, including diesel, methanol (see: direct-methanol fuel cells) and chemical hydrides. The waste products with these types of fuel are carbon dioxide and water.
The materials used in fuel cells differ by type. The electrode–bipolar plates are usually made of metal, nickel or carbon nanotubes, and are coated with a catalyst (like platinum, nano iron powders or palladium) for higher efficiency. Carbon paper separates them from the electrolyte. The electrolyte could be ceramic or a membrane.
A typical PEM fuel cell produces a voltage from 0.6 V to 0.7 V at full rated load. Voltage decreases as current increases, due to several factors:
- Activation loss
- Ohmic loss (voltage drop due to resistance of the cell components and interconnects)
- Mass transport loss (depletion of reactants at catalyst sites under high loads, causing rapid loss of voltage)[3]
To deliver the desired amount of energy, the fuel cells can be combined in series and parallel circuits, where series yield higher voltage, and parallel allows a stronger current to be drawn. Such a design is called a fuel cell stack. Further, the cell surface area can be increased, to allow stronger current from each cell.
http://en.wikipedia.org/wiki/Fuel_cellfuel cell vehicles (FCVs)
This emerging technology has the potential to significantly reduce energy use and harmful emissions, as well as our dependence on foreign oil. FCVs will have other benefits as well.
A Radical Departure
FCVs represent a radical departure from vehicles with conventional internal combustion engines. Like battery-electric vehicles, FCVs are propelled by electric motors. But while battery electric vehicles use electricity from an external source (and store it in a battery), FCVs create their own electricity. Fuel cells onboard the vehicle create electricity through a chemical process using hydrogen fuel and oxygen from the air.
FCVs can be fueled with pure hydrogen gas stored onboard in high-pressure tanks. They also can be fueled with hydrogen-rich fuels; such as methanol, natural gas, or even gasoline; but these fuels must first be converted into hydrogen gas by an onboard device called a "reformer."
FCVs fueled with pure hydrogen emit no pollutants; only water and heat; while those using hydrogen-rich fuels and a reformer produce only small amounts of air pollutants. In addition, FCVs can be twice as efficient as similarly sized conventional vehicles and may also incorporate other advanced technologies to increase efficiency.
Fuel cell
A fuel cell is an electrochemical energy conversion device. It produces electricity from various external quantities of fuel (on the anode side) and oxidant (on the cathode side). These react in the presence of an electrolyte. Generally, the reactants flow in and reaction products flow out while the electrolyte remains in the cell. Fuel cells can operate virtually continuously as long as the necessary flows are maintained.
Fuel cells are different from batteries in that they consume reactant, which must be replenished, while batteries store electrical energy chemically in a closed system. Additionally, while the electrodes within a battery react and change as a battery is charged or discharged, a fuel cell's electrodes are catalytic and relatively stable.
Many combinations of fuel and oxidant are possible. A hydrogen cell uses hydrogen as fuel and oxygen as oxidant. Other fuels include hydrocarbons and alcohols. Other oxidants include air, chlorine and chlorine dioxide.
http://en.wikipedia.org/wiki/Fuel_cell
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